FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2013338710> ?p ?o ?g. }

• W2013338710 endingPage "16" @default.
• W2013338710 startingPage "11" @default.
• W2013338710 abstract "The thermal degradation kinetics of poly (ε-caprolactone) (PCL) in solution was investigated at various temperatures (170–245 °C). The degradation was also investigated by pyrolysis at various temperatures (280–330 °C). The time evolution of molecular weight distribution (MWD) was obtained using gel permeation chromatography. It was observed that in pyrolysis, PCL degrades by specific chain end scission by unzipping of monomers from the hydroxyl end of the polymer chains. In contrast, the degradation of PCL in solution is by random chain scission. A continuous distribution kinetics model is proposed to explain the observed behaviour under both conditions. The activation energy, determined from the temperature dependence of rate coefficients, was 61 kJ/mol and 201 kJ/mol for the degradation in solution and by pyrolysis, respectively." @default.
• W2013338710 created "2016-06-24" @default.
• W2013338710 creator A5056908964 @default.
• W2013338710 creator A5081390178 @default.
• W2013338710 date "2003-01-01" @default.
• W2013338710 modified "2023-10-16" @default.
• W2013338710 title "Thermal degradation of poly (ε-caprolactone)" @default.
• W2013338710 cites W2051603731 @default.
• W2013338710 cites W2063015943 @default.
• W2013338710 cites W2130643415 @default.
• W2013338710 cites W2136351682 @default.
• W2013338710 cites W2162786412 @default.
• W2013338710 doi "https://doi.org/10.1016/s0141-3910(02)00376-2" @default.
• W2013338710 hasPublicationYear "2003" @default.
• W2013338710 type Work @default.
• W2013338710 sameAs 2013338710 @default.
• W2013338710 citedByCount "76" @default.
• W2013338710 countsByYear W20133387102012 @default.
• W2013338710 countsByYear W20133387102013 @default.
• W2013338710 countsByYear W20133387102014 @default.
• W2013338710 countsByYear W20133387102015 @default.
• W2013338710 countsByYear W20133387102016 @default.
• W2013338710 countsByYear W20133387102017 @default.
• W2013338710 countsByYear W20133387102018 @default.
• W2013338710 countsByYear W20133387102019 @default.
• W2013338710 countsByYear W20133387102020 @default.
• W2013338710 countsByYear W20133387102021 @default.
• W2013338710 countsByYear W20133387102022 @default.
• W2013338710 countsByYear W20133387102023 @default.
• W2013338710 crossrefType "journal-article" @default.
• W2013338710 hasAuthorship W2013338710A5056908964 @default.
• W2013338710 hasAuthorship W2013338710A5081390178 @default.
• W2013338710 hasConcept C121332964 @default.
• W2013338710 hasConcept C127413603 @default.
• W2013338710 hasConcept C147789679 @default.
• W2013338710 hasConcept C148898269 @default.
• W2013338710 hasConcept C158117686 @default.
• W2013338710 hasConcept C15920480 @default.
• W2013338710 hasConcept C159985019 @default.
• W2013338710 hasConcept C161790260 @default.
• W2013338710 hasConcept C166940927 @default.
• W2013338710 hasConcept C178790620 @default.
• W2013338710 hasConcept C185592680 @default.
• W2013338710 hasConcept C188027245 @default.
• W2013338710 hasConcept C192562407 @default.
• W2013338710 hasConcept C204530211 @default.
• W2013338710 hasConcept C2779679103 @default.
• W2013338710 hasConcept C2781111393 @default.
• W2013338710 hasConcept C3044715 @default.
• W2013338710 hasConcept C36759035 @default.
• W2013338710 hasConcept C41008148 @default.
• W2013338710 hasConcept C41625074 @default.
• W2013338710 hasConcept C42360764 @default.
• W2013338710 hasConcept C50670333 @default.
• W2013338710 hasConcept C521977710 @default.
• W2013338710 hasConcept C55493867 @default.
• W2013338710 hasConcept C62520636 @default.
• W2013338710 hasConcept C63179538 @default.
• W2013338710 hasConcept C76155785 @default.
• W2013338710 hasConcept C95121573 @default.
• W2013338710 hasConcept C97355855 @default.
• W2013338710 hasConceptScore W2013338710C121332964 @default.
• W2013338710 hasConceptScore W2013338710C127413603 @default.
• W2013338710 hasConceptScore W2013338710C147789679 @default.
• W2013338710 hasConceptScore W2013338710C148898269 @default.
• W2013338710 hasConceptScore W2013338710C158117686 @default.
• W2013338710 hasConceptScore W2013338710C15920480 @default.
• W2013338710 hasConceptScore W2013338710C159985019 @default.
• W2013338710 hasConceptScore W2013338710C161790260 @default.
• W2013338710 hasConceptScore W2013338710C166940927 @default.
• W2013338710 hasConceptScore W2013338710C178790620 @default.
• W2013338710 hasConceptScore W2013338710C185592680 @default.
• W2013338710 hasConceptScore W2013338710C188027245 @default.
• W2013338710 hasConceptScore W2013338710C192562407 @default.
• W2013338710 hasConceptScore W2013338710C204530211 @default.
• W2013338710 hasConceptScore W2013338710C2779679103 @default.
• W2013338710 hasConceptScore W2013338710C2781111393 @default.
• W2013338710 hasConceptScore W2013338710C3044715 @default.
• W2013338710 hasConceptScore W2013338710C36759035 @default.
• W2013338710 hasConceptScore W2013338710C41008148 @default.
• W2013338710 hasConceptScore W2013338710C41625074 @default.
• W2013338710 hasConceptScore W2013338710C42360764 @default.
• W2013338710 hasConceptScore W2013338710C50670333 @default.
• W2013338710 hasConceptScore W2013338710C521977710 @default.
• W2013338710 hasConceptScore W2013338710C55493867 @default.
• W2013338710 hasConceptScore W2013338710C62520636 @default.
• W2013338710 hasConceptScore W2013338710C63179538 @default.
• W2013338710 hasConceptScore W2013338710C76155785 @default.
• W2013338710 hasConceptScore W2013338710C95121573 @default.
• W2013338710 hasConceptScore W2013338710C97355855 @default.
• W2013338710 hasIssue "1" @default.
• W2013338710 hasLocation W20133387101 @default.
• W2013338710 hasOpenAccess W2013338710 @default.
• W2013338710 hasPrimaryLocation W20133387101 @default.
• W2013338710 hasRelatedWork W1545770818 @default.
• W2013338710 hasRelatedWork W2000232332 @default.
• W2013338710 hasRelatedWork W2000799279 @default.
• W2013338710 hasRelatedWork W2013338710 @default.

• next