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• W2013360147 abstract "A novel route to the neuroexcitatory amino acid, kainic acid, is developed. The key concept derives from a ruthenium-catalyzed cycloisomerization of a tethered alkyne−propargyl alcohol to form a cylic 2-vinyl-1-acyl compound. A single stereocenter introduced by an asymmetric reduction of a ketone sets the stage for all the other stereocenters. A novel 1,6-addition of silyl cuprate serves to install a hydroxyl group at the diene termines." @default.
• W2013360147 created "2016-06-24" @default.
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• W2013360147 date "2003-04-08" @default.
• W2013360147 modified "2023-10-09" @default.
• W2013360147 title "Ruthenium-Catalyzed Alkyne−Propargyl Alcohol Addition. An Asymmetric Total Synthesis of (+)-α-Kainic Acid" @default.
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• W2013360147 doi "https://doi.org/10.1021/ol034241y" @default.
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