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- W2013364256 abstract "Abstract An ion-pair compound, 1,10-bis(1-methylimidazolium)decane bis(maleonitriodithiolato)nickelate ( 1 ), was synthesized and single crystal structurally characterized. The bis(maleonitriodithiolato)nickelate anions and dication formed the layered stacks in the crystal. A dielectric relaxation was observed in low-frequency region and could be attributed to local dipole or molecular motion in 1 . The relaxation process for 1 was fitted using Cole–Cole model function. Furthermore, this ion-pair compound shows novel dielectric bistability and dielectric phase transition around 90 °C, which is probably arise from the disorder-to-order transformation of alkyl chains and the conformation rotation of imidazolyl rings. This study provided a new strategy for the design of dielectric bistable system." @default.
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- W2013364256 date "2014-09-01" @default.
- W2013364256 modified "2023-09-27" @default.
- W2013364256 title "Observation of novel dielectric bistability in a nickel-dithiolene ion-pair compound" @default.
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- W2013364256 doi "https://doi.org/10.1016/j.synthmet.2014.06.015" @default.
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