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• W2013364898 abstract "In situ DRIFTS study of toluene oxidation over V–Ti–O catalyst at ambient temperature was presented. Physisorbed benzaldehyde, benzoic acid, benzoate, vanadyl species and carbon dioxide were detected. An analysis of the vanadyl species band and XPS characterization were used to illustrate the reaction route. A reaction mechanism is proposed: monomeric VOx is firstly reduced by the adsorbed species, then oxygen transfers from bulk V2O5 to monomeric VOx for compensation, and the oxygen-deficient bulk V2O5 replenishes oxygen from gas phase. The transference of oxygen from bulk V2O5 to reduced VOx is deemed as the rate determining step below 90 °C." @default.
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• W2013364898 date "2011-10-01" @default.
• W2013364898 modified "2023-10-16" @default.
• W2013364898 title "In situ DRIFTS study on the catalytic oxidation of toluene over V2O5/TiO2 under mild conditions" @default.
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• W2013364898 doi "https://doi.org/10.1016/j.catcom.2011.07.024" @default.
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