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• W2013366427 abstract "Trivalent transition metal ions (Cr(3+), Fe(3+)) doped CdO nanopowders via sonication in the presence of Sodium lauryl sulfate as stabilizing agent were synthesized and characterized. Powder XRD studies indicate that the obtained CdO has a cubic phase and concluded that the trivalent ions doping induced the lattice constants to change some extent. Optical absorption spectra exhibited the characteristic bands of Cr(3+) and Fe(3+) ions in octahedral site symmetry. Crystal field (Dq) and inter-electronic repulsion (B and C) parameters are evaluated for Cr(3+) doped CdO nanopowders as Dq=1540, B=619 and C=3327 cm(-1) and for Fe(3+) doped CdO nanopowders Dq=920, B=690, C=2750 cm(-1). EPR spectra of the Cr(3+) and Fe(3+) doped CdO nanopowders exhibited resonances at g=1.973 and g=2 respectively which indicate distorted octahedral site for both ions with the host. Photoluminescence spectra shows the emission bands in violet and bluish green regions for Cr(3+) doped CdO, ultraviolet and blue emissions for Fe(3+) doped CdO nanopowders. The CIE chromaticity coordinates were also evaluated from the emission spectrum. FT-IR spectra indicate the presence of various functional groups of host lattice." @default.
• W2013366427 created "2016-06-24" @default.
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• W2013366427 date "2014-03-01" @default.
• W2013366427 modified "2023-10-18" @default.
• W2013366427 title "Synthesis and spectral characterizations of trivalent ions (Cr3+, Fe3+) doped CdO nanopowders" @default.
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• W2013366427 doi "https://doi.org/10.1016/j.saa.2013.11.018" @default.
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