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• W2013366897 endingPage "364" @default.
• W2013366897 startingPage "355" @default.
• W2013366897 abstract "The new germanium-containing ferrocene and ferrocenophane derivatives (2,3,4,5-tetramethylbuta-1,3-dien-1,4-diyl)-germa-[1]ferrocenophane (2), 2-(2,3,4,5-tetramethylbuta-1,3-dien-1,4-diyl)-1,3-dithia-2-germa-[3]ferrocenophane (3), 1,1′-bis(1-ethoxy-2,3,4,5-tetramethyl-1-germacyclopenta-2,4-dienyl)-ferrocene (6), 1,3-bis(2,3,4,5-tetramethylbuta-1,3-dien-1,4-diyl)-1,3-digerma-2-oxo-[3]ferrocenophane (7), 1,1′-bis(1-hydrido-2,3,4,5-tetramethyl-1-germacyclopenta-2,4-dienyl)-ferrocene (8) and 1,2-bis(2,3,4,5-tetramethylbuta-1,3-dien-1,4-diyl)-digerma-[2]ferrocenophane (9) have been prepared starting from the dichlorogermol 1. The synthesis of the known ferrocenophanes dichloro-(ferrocene-1,1′-dithiolato)-germane (10a) and dichloro-(ferrocene-1,1′-dithiolato)-stannane (10b) was improved. X-ray crystal structural studies of 2 (C18H20FeGe, a=10.907(4), b=11.040(4), c=13.771(5) Å, β=110.87°, monoclinic, C2/c (No. 15), Z=4), 3 (C18H20FeGeS2, a=8.104(3), b=8.593(4), c=13.177(6) Å, α=70.79(4), β=77.56(3), γ=85.80(3) Å triclinic, P1̄ (No. 2), Z=2), 7 (C26H32FeGe2O, a=18.95(2), b=8.557(6), c=16.69(6) Å, β=110.65(6)°, monoclinic, C2/c (No. 15), Z=4), 9 (C26H32FeGe2, a=11.209(6), b=10.839(5), c=19.819(10) Å, β=92.89(2), γ=90°, monoclinic, P21/n (No. 14), Z=4), 10a (C10H8FeGeS2, a=10.873(5), b=7.417(4), c=16.415(10) Å, orthorhombic, Pca21 (No. 29), Z=4), 12a (C20H16Fe2GeS4, a=7.459(4), b=10.921(5), c=23.552(12) Å, orthorhombic, Pbcn (No. 60), Z=4) and 12b (C20H16Fe2SnS4, a=7.484(4), b=10.953(6), c=23.917(12) Å, orthorhombic, Pbcn (No. 60), Z=4) and cyclovoltammetric characterizations for all ferrocene-containing compounds have been carried out." @default.
• W2013366897 created "2016-06-24" @default.
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• W2013366897 date "1999-08-01" @default.
• W2013366897 modified "2023-10-02" @default.
• W2013366897 title "Germanium-containing ferrocenes and ferrocenophanes. Potential precursors for ring-opening polymerizations and ‘germaferrocenes’" @default.
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• W2013366897 doi "https://doi.org/10.1016/s0020-1693(99)00133-4" @default.
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