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- W2013368501 abstract "Electrochemical or chemical oxidation of pyrrole-containing complex anions of iron cyanide or iron chloride results in the formation of films or powders of conducting polypyrroles. Freshly prepared films exhibit an additional IR band at ca 1630–1640 cm−1, slowly disappearing in air and not observed in previously studies polypyrrole-based systems. It is possible that this new band is associated with the existence of a CN bond in dehydrogenated pyrrole rings which are transformed into regular pyrrole rings, probably due to the protonation reaction occurring in air and simultaneous bond rearrangement. The polypyrrole structure favours the presence of Fe(CN)64− over Fe(CN)63− since the former is the only iron species detected by Mössbauer spectroscopy in electrochemically prepared samples. It is also the dominant iron species in the samples oxidized chemically. The polypyrrole-containing Fe(CN)64− is more ordered than those containing monovalent anions, as evidence by X-ray diffraction studies. High-spin eron complexes can be inserted into polypyrrole during electrochemical oxidation of pyrrole in non-aqueous solutions containing LiCl/FeCl3. The inserted species exhibit Mössbauer parameters characteristic of slightly distorted FeCl4−." @default.
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- W2013368501 date "1987-01-01" @default.
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- W2013368501 title "Synthesis and characterization of conducting polypyrrole-containing iron complexes" @default.
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- W2013368501 doi "https://doi.org/10.1016/0022-3697(87)90152-1" @default.
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