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- W2013396076 abstract "The (222) and ($overline{2}overline{2}overline{2}$) integrated intensities were measured in the absence of simultaneous reflections, using $mathrm{C}mathrm{o}ensuremath{-}Kensuremath{alpha}$ radiation. While the integrated intensity calculated using free-atom scattering factors is the same for both (222) and ($overline{2}overline{2}overline{2}$), the measured values were, respectively, 86 and 66% higher than the calculated one. The fact that both experimental intensities are higher than the calculated value indicates that a net transfer of charge occurs from Ga to As. This conclusion is in agreement with a previous result obtained by DeMarco and Weiss from the measurement of the (200) reflection, but disagrees with observations based on piezoelectric measurements and Fourier synthesis of the charge distribution. The asymmetry between (222) and ($overline{2}overline{2}overline{2}$) is consistent with the existence of electron bridges between first neighbors, thus providing direct evidence of the covalent character of the bonding. It is proposed to exploit the different reflecting powers for the (222) and ($overline{2}overline{2}overline{2}$) planes as an alternative method for determining the absolute polarity of a (111) face, using a characteristic x-ray radiation." @default.
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- W2013396076 date "1971-06-15" @default.
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- W2013396076 title "X-Ray Investigation of Bond-Charge Density in Gallium Arsenide" @default.
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- W2013396076 doi "https://doi.org/10.1103/physrevb.3.4308" @default.
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