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- W2013407763 abstract "A flow-injection system is described for the selective determination of arsenic(III) and arsenic(V) (0.05–20 ng) in a 100μl sample volume by hydride generation and atomic absorption spectrometry. An electrically heated aluminium column was used to generate the arsine in an alkaline medium. Recoveries averaged 97–99% for arsenic(III) and 95–98% for arsenic(V) with relative standard deviations of less than 4.3% in each instance. The detection limit was 0.25 μg l−1 (25 pg) of arsenic in both instances. This method was relatively free from interferences and was applied successfully to the determination of arsenic(III) and arsenic(V) in trout fishery water samples. The data obtained were compared with those produced by a hydride generation-cold trapping atomic absorption spectrometric detection method, using sodium tetrahydroborate(III) in hydrochloric acid. The results obtained by both methods were in close agreement, within 96-102%" @default.
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- W2013407763 date "1992-05-01" @default.
- W2013407763 modified "2023-10-10" @default.
- W2013407763 title "Flow-injection atomic spectrometric determination of inorganic arsenic(III) and arsenic(V) species by use of an aluminium-column arsine generator and cold-trapping arsine collection" @default.
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- W2013407763 doi "https://doi.org/10.1016/0003-2670(92)80181-6" @default.
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