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• W2013429162 abstract "The synthesis of star-shaped molecules, comprising a pyrene core with tetrakis(phenylethynyl) arms substituted with N,N-dimethylamino and propyl groups (1–5), is reported. The electrochemical and photophysical properties of 1–5 depend on the number of N,N-dimethylamino groups on the tetrakis(phenylethynyl)pyrene framework. In electrogenerated chemiluminescence (ECL) studies, the spectra of 4 and 5 show red-shifts and band broadening; in contrast, 1 exhibits a typical high-intensity pyrene ECL emission. It was confirmed that the ECL spectra arise from the intramolecular charge transfer (ICT) induced by the annihilation of radical ions owing to the presence of a strong donor." @default.
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• W2013429162 date "2013-07-01" @default.
• W2013429162 modified "2023-10-17" @default.
• W2013429162 title "Electrogenerated chemiluminescence of N,N-dimethylamino functionalized tetrakis(phenylethynyl)pyrenes" @default.
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• W2013429162 doi "https://doi.org/10.1016/j.tet.2013.05.010" @default.
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