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• W2013434706 abstract "Electrode polarization complicates low-frequency measurements of the dielectric response of electrolyte solutions and colloidal suspensions. To deal with this longstanding problem, a new dielectric cell was developed along with a model based on the standard electrokinetic theory. The parallel plate cell utilizes a thin chamber that is easily filled and emptied; different chamber thicknesses are readily accommodated. The analytical form of the theoretical impedance model makes data analysis straightforward. Using standard electrolytes, the device and the theoretical model were tested over a wide range of frequencies for several electrolyte concentrations. Excellent agreement was found between the theory and the experimental data. The methodology developed to account for polarization effects exhibits a significant improvement over the conventional approaches and points up a deficiency in often-used equivalent circuit models." @default.
• W2013434706 created "2016-06-24" @default.
• W2013434706 creator A5002712073 @default.
• W2013434706 creator A5087806271 @default.
• W2013434706 date "2003-01-01" @default.
• W2013434706 modified "2023-09-23" @default.
• W2013434706 title "A broad frequency range dielectric spectrometer for colloidal suspensions: cell design, calibration, and validation" @default.
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• W2013434706 doi "https://doi.org/10.1016/s0021-9797(02)00029-2" @default.
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