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- W2013450232 abstract "Abstract The 10 K crystal structures of high-T c RBa 2 Cu 3 O 7 (R = Y and rare earths) ceramic materials investigated by neutron diffraction were consistently analysed concerning systematic trends. Several interionic distances exhibit the well known lanthanide contraction behaviour, i. e., a linear relationship with the ionic radii of trivalent rare-earth ions. The only exceptions are associated with the apex oxygen O(1) ions: the chain copper Cu(1)-O(1) distances are constant, and the plane copper Cu(2)-O(1) distances are increasing across the rare-earth series. For R = Pr the 4f-CuO 2 valence band hybridization effects are found to be highly anisotropic, since exclusively the interionic distances involving the b-direction (i. e., the chain direction) indicate that the Pr ions have an intermediate valence of about +3.4." @default.
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- W2013450232 date "1993-05-01" @default.
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- W2013450232 title "A systematic neutron diffraction study of RBa2Cu3O7 (R = yttrium and rare earths) high-Tc superconductors" @default.
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- W2013450232 doi "https://doi.org/10.1016/0925-8388(93)90809-2" @default.
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