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- W2013451102 abstract "Abstract Iron(III) deuteroporphyrin dimethyl ester is oxidized to the radical cation form by the peroxyl radicals CH 2 (OH)O 2 − and (CH 3 ) 2 C(OH)O 2 − generated by pulse radiolysis of air saturated aqueous solutions of methanol and 2-propanol, respectively. Oxidation by CH 2 (OH)O 2 − radicals proceeds with k = 1×10 7 M −1 s −1 independent of pH . In contrast, the electron-transfer reaction of (CH 3 ) 2 C(OH)O 2 −1 is pH -dependent. A reaction scheme, which may apply to all peroxyl radicals depending on relative rate constants, is proposed. It involves the formation of an iron porphyrin peroxyl radical adduct that decays by acid-dependent and acid-independent routes." @default.
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- W2013451102 title "Oxidation of FeIII porphyrins by peroxyl radicals derived from 2-propanol and methanol. Evidence for acid-dependent and acid-independent pathways" @default.
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- W2013451102 doi "https://doi.org/10.1016/0009-2614(85)87148-7" @default.
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