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- W2013470525 abstract "Single crystals of a new complex phosphate, calcium sodium vanadium phosphate, Ca8.42Na1.16V(PO4)7, have been grown from a melt under an inert atmosphere. The crystal structure has rhombohedral (R3c) symmetry and belongs to the whitlockite structure type. Vanadium(III) ions occupy nearly regular octahedral sites (M5 with 3 point symmetry), which share corners with six PO4 tetrahedra to form isolated units. The calcium ions occupy eight- and nine-coordinated sites. The sodium ions partially occupy one octahedral position and share one nine-coordinated position with a Ca atom." @default.
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- W2013470525 date "2006-01-21" @default.
- W2013470525 modified "2023-09-27" @default.
- W2013470525 title "A new whitlockite, Ca<sub>8.42</sub>Na<sub>1.16</sub>V(PO<sub>4</sub>)<sub>7</sub>" @default.
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- W2013470525 doi "https://doi.org/10.1107/s0108270105039041" @default.
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