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- W2013498246 abstract "The effect of Cr3+ on the cathodic current efficiency (CE), deposit morphology, crystallographic orientations and polarisation behaviour during nickel electrodeposition from acidic sulfate solutions containing boric acid was investigated. A progressive decrease in CE was seen with increase in Cr3+ concentration showing a maximum decrease in CE of ∼10–13% at concentration ∼100 mg dm−3. The presence of Cr3+ did not change the fcc structure of the electrodeposited nickel but affected the peak intensities of the crystal planes. Polarisation of the cathode was seen in the presence of Cr3+ in the electrolyte along with a shift in the electroreduction potential of nickel (II) ion towards more negative values. The effect of Cr3+ on the electrokinetic parameters: Tafel slope (b), transfer coefficient (α) and exchange current density (i0) has also been investigated." @default.
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- W2013498246 date "2002-07-01" @default.
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- W2013498246 title "Effect of Cr3+ on the electrodeposition of nickel from acidic sulfate solutions" @default.
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- W2013498246 doi "https://doi.org/10.1016/s0892-6875(02)00076-6" @default.
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