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• W2013499477 abstract "A kinetic analysis under non-isothermal conditions has been performed on europium-doped phosphate glasses with molar composition 20.42 Li2O–10.25 Al2O3–58.49 P2O5–7.23 BaO–1.44 La2O3–2.16 Eu2O3 and particle size <30 µm, >50 µm. Differential scanning calorimetry measurements at four heating rates, from room temperature up to 900 °C using synthetic air have revealed that no significant mass change occurs during the heat treatment, as normally expected for glass samples. The step changes in heat flow signals are associated with the presence of three important effects: the first one, that occurs as a slope corresponds to the glass transition effect (Tg) is followed by two exothermic peaks, first of them more pronounced, associated with the first crystallization process (Tp1), while, the second one, lower in intensity corresponds to the second crystallization (Tp2) process. As expected, all peaks (Tg, Tp1 and Tp2) increase with the increasing of the heating rate. Both the activation energy of crystallization process and the crystallization mechanism were comparatively analyzed by two free-model estimations and using the formal theory of transformations for heterogeneous nucleation." @default.
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• W2013499477 date "2014-09-01" @default.
• W2013499477 modified "2023-10-18" @default.
• W2013499477 title "Non-isothermal free-models kinetic analysis on crystallization of europium-doped phosphate glasses" @default.
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• W2013499477 doi "https://doi.org/10.1016/j.ceramint.2014.04.089" @default.
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