FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2013516114> ?p ?o ?g. }

• W2013516114 endingPage "3745" @default.
• W2013516114 startingPage "3733" @default.
• W2013516114 abstract "We measured the adsorption of Cu(II) onto kaolinite from pH 3–7 at constant ionic strength. EXAFS spectra show that Cu(II) adsorbs as (CuO4Hn)n−6 and binuclear (Cu2O6Hn)n−8 inner-sphere complexes on variable-charge ≡AlOH sites and as Cu2+ on ion exchangeable ≡X--H+ sites. Sorption isotherms and EXAFS spectra show that surface precipitates have not formed at least up to pH 6.5. Inner-sphere complexes are bound to the kaolinite surface by corner-sharing with two or three edge-sharing Al(O,OH)6 polyhedra. Our interpretation of the EXAFS data are supported by ab initio (density functional theory) geometries of analog clusters simulating Cu complexes on the {110} and {010} crystal edges and at the ditrigonal cavity sites on the {001}. Having identified the bidentate (≡AlOH)2Cu(OH)20, tridentate (≡Al3O(OH)2)Cu2(OH)30 and ≡X--Cu2+ surface complexes, the experimental copper(II) adsorption data can be fit to the reactions 2≡AlOH+Cu2++2H2O=(≡AlOH)2Cu(OH)20+2H+3(≡AlOH)+2Cu2++3H2O=(≡Al3O(OH)2)Cu2(OH)30+4H+ and (A1)≡X−--H++Cu2+=≡X−--Cu2++X+." @default.
• W2013516114 created "2016-06-24" @default.
• W2013516114 creator A5012135074 @default.
• W2013516114 creator A5026090313 @default.
• W2013516114 date "2005-08-01" @default.
• W2013516114 modified "2023-09-27" @default.
• W2013516114 title "Surface complexation model for multisite adsorption of copper(II) onto kaolinite" @default.
• W2013516114 cites W1037763783 @default.
• W2013516114 cites W182588465 @default.
• W2013516114 cites W1966428360 @default.
• W2013516114 cites W1970028655 @default.
• W2013516114 cites W1973106790 @default.
• W2013516114 cites W1989633791 @default.
• W2013516114 cites W1990407093 @default.
• W2013516114 cites W1992010901 @default.
• W2013516114 cites W1998874847 @default.
• W2013516114 cites W2000770004 @default.
• W2013516114 cites W2002088075 @default.
• W2013516114 cites W2005102486 @default.
• W2013516114 cites W2016989366 @default.
• W2013516114 cites W2017117460 @default.
• W2013516114 cites W2026156643 @default.
• W2013516114 cites W2026967572 @default.
• W2013516114 cites W2030178449 @default.
• W2013516114 cites W2038533471 @default.
• W2013516114 cites W2041143366 @default.
• W2013516114 cites W2057379306 @default.
• W2013516114 cites W2062346731 @default.
• W2013516114 cites W2069256274 @default.
• W2013516114 cites W2069770779 @default.
• W2013516114 cites W2070094582 @default.
• W2013516114 cites W2070182138 @default.
• W2013516114 cites W2078772463 @default.
• W2013516114 cites W2081563476 @default.
• W2013516114 cites W2082547953 @default.
• W2013516114 cites W2082575869 @default.
• W2013516114 cites W2089629101 @default.
• W2013516114 cites W2091558236 @default.
• W2013516114 cites W2091698129 @default.
• W2013516114 cites W2101265995 @default.
• W2013516114 cites W2103578520 @default.
• W2013516114 cites W2119509015 @default.
• W2013516114 cites W2145605494 @default.
• W2013516114 cites W2150345533 @default.
• W2013516114 cites W2155809931 @default.
• W2013516114 cites W2161645855 @default.
• W2013516114 cites W2165092102 @default.
• W2013516114 cites W2301872621 @default.
• W2013516114 cites W3206606417 @default.
• W2013516114 cites W329981192 @default.
• W2013516114 cites W4256225345 @default.
• W2013516114 doi "https://doi.org/10.1016/j.gca.2004.12.029" @default.
• W2013516114 hasPublicationYear "2005" @default.
• W2013516114 type Work @default.
• W2013516114 sameAs 2013516114 @default.
• W2013516114 citedByCount "78" @default.
• W2013516114 countsByYear W20135161142012 @default.
• W2013516114 countsByYear W20135161142013 @default.
• W2013516114 countsByYear W20135161142014 @default.
• W2013516114 countsByYear W20135161142015 @default.
• W2013516114 countsByYear W20135161142016 @default.
• W2013516114 countsByYear W20135161142017 @default.
• W2013516114 countsByYear W20135161142018 @default.
• W2013516114 countsByYear W20135161142019 @default.
• W2013516114 countsByYear W20135161142020 @default.
• W2013516114 countsByYear W20135161142021 @default.
• W2013516114 countsByYear W20135161142022 @default.
• W2013516114 countsByYear W20135161142023 @default.
• W2013516114 crossrefType "journal-article" @default.
• W2013516114 hasAuthorship W2013516114A5012135074 @default.
• W2013516114 hasAuthorship W2013516114A5026090313 @default.
• W2013516114 hasConcept C107861141 @default.
• W2013516114 hasConcept C115624301 @default.
• W2013516114 hasConcept C119824511 @default.
• W2013516114 hasConcept C121332964 @default.
• W2013516114 hasConcept C145148216 @default.
• W2013516114 hasConcept C147789679 @default.
• W2013516114 hasConcept C150394285 @default.
• W2013516114 hasConcept C178516000 @default.
• W2013516114 hasConcept C178790620 @default.
• W2013516114 hasConcept C179104552 @default.
• W2013516114 hasConcept C184651966 @default.
• W2013516114 hasConcept C185592680 @default.
• W2013516114 hasConcept C187428577 @default.
• W2013516114 hasConcept C199289684 @default.
• W2013516114 hasConcept C2182769 @default.
• W2013516114 hasConcept C2779899878 @default.
• W2013516114 hasConcept C544778455 @default.
• W2013516114 hasConcept C54998646 @default.
• W2013516114 hasConcept C62520636 @default.
• W2013516114 hasConcept C8010536 @default.
• W2013516114 hasConceptScore W2013516114C107861141 @default.
• W2013516114 hasConceptScore W2013516114C115624301 @default.
• W2013516114 hasConceptScore W2013516114C119824511 @default.
• W2013516114 hasConceptScore W2013516114C121332964 @default.
• W2013516114 hasConceptScore W2013516114C145148216 @default.
• W2013516114 hasConceptScore W2013516114C147789679 @default.
• W2013516114 hasConceptScore W2013516114C150394285 @default.

• next