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- W2013525048 abstract "Although the compound RhMe(CO){MeC(CH2PPh2)3}(1) is normally inert to methyl iodide, chlorotrimethyltin and acetone, it reacts in the presence of trimethylphosphine with (a) methyl iodide to form the cationic complex [Rh(CO)(PMe3){MeC(CH2PPh2)3}]+(2), methane, and ethylene but not ethane, (b) chlorotrimethyltin to form (2) and tetramethyltin, and (c) acetone to form (2) and t-butoxide; the role of the trimethylphosphine seems to involve substituting one arm of the triphosphine, thus rendering the Rh–Me moiety more reactive towards electrophilic reagents." @default.
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- W2013525048 date "1989-01-01" @default.
- W2013525048 modified "2023-09-26" @default.
- W2013525048 title "Alkyl group transfer from rhodium(I) to electrophilic reagents; inducement by a tertiary phosphine" @default.
- W2013525048 doi "https://doi.org/10.1039/c39890001008" @default.
- W2013525048 hasPublicationYear "1989" @default.
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