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• W2013551749 abstract "A single-crystal EPR study of tetraphenylarsoniumtetrachloro nitrido-technetate (VI), (Ph4As) [Tc15NCl4], diamagnetically diluted by the isoelectronic oxotechnetate (V) complex, and the crystal structure of the host complex are reported. (Ph4As) [TcOCl4] crystallizes tetragonal, space group P4/n, Z=2 with a=b= 12.670(1) and c=7.824(1) Å. The anion possesses C4v symmetry. The EPR spectra are typical of an ion with a 4d1 configuration. At low temperatures very complex 35,37Cl and 15N ligand hyperfine patterns are observed. The 99Tc, 35,37Cl and 15N hyperfine data are analyzed to evaluate the electron spin delocalization: 20% of the spin density is localized in mainly the 3p orbitals of the Cl atoms." @default.
• W2013551749 created "2016-06-24" @default.
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• W2013551749 date "1990-05-01" @default.
• W2013551749 modified "2023-10-15" @default.
• W2013551749 title "Single-crystal EPR, 35,37Cl and 14,15N ENDOR and ESEEM studies on (Ph4As)[TcVINCl4/TcVOCl4]. I. Single-crystal EPR on (Ph4As)[Tc14,15NCl4/TcOCl4], and crystal structure of (Ph4As)[TcOCl4]" @default.
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• W2013551749 doi "https://doi.org/10.1016/0301-0104(90)85008-k" @default.
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