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- W2013554895 abstract "In a potentiometric titration of a solution that contains both the reduced form Red 2 and the oxidized form Ox 2 of a redox couple, at concentrations of c 0 Red 2 M and c 0 Ox 2 M , respectively, using as reagent a solution that contains the oxidized and reduced forms Ox 1 and Red 1 at concentrations of c Ox 1 M and c Red 1 M , respectively, the reaction that occurs is n Red 2 + n 2 Ox 1 = n 1 Ox 2 + n 2 Red 1 ; K t = exp[ n 1 n 2 ( E 0 1 ′– E 0 2 ′)/0.02569] if all of the reactants and products are monomeric and if the titration is done at 25°C. By applying weighted non-linear regression analysis to the data obtained in such a titration, if c Ox 1 is known, it is possible to evaluate four parameters: c 0 Red 2 , c 0 Ox 2 , and the formal potentials E 0 2 ′ and E 0 1 ′ for the couple titrated and the reagent couple, respectively. For the common situation in which n 1 and n 2 are equal, this paper describes the ways in which the precisions of all four parameters depend, over a wide range of conditions, on their values and on the precisions of measurement of the volume of reagent and the potential of the indicator electrode." @default.
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- W2013554895 date "1987-01-01" @default.
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- W2013554895 title "Factors affecting the precision of a new method for determining the reduced and oxidized forms of a redox couple by a single potentiometric titration" @default.
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- W2013554895 doi "https://doi.org/10.1016/s0003-2670(00)84768-6" @default.
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