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- W2013567048 abstract "In situ high-energy X-ray diffraction was carried out to investigate the structural transformation of lithium cobalt oxides during the solid-state synthesis. Two allotropic phases were observed during the synthesis process; Li2Co2O4 with a spinel structure was formed within the temperature window between 450 °C and 650 °C, beyond which Li2Co2O4 was converted to its hexagonal counterpart, layered LiCoO2, through a cation exchange between Li and Co. In electrochemical tests, the Li2Co2O4 was estimated to have a very low reversible capacity, ∼20 mAh g−1, and a high initial irreversible capacity loss of about 80 mAh g−1. An interfacial phase between layered LiCoO2 domain and spinel Li2Co2O4 domain was also identified by ex situ high-resolution X-ray diffraction." @default.
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- W2013567048 date "2014-12-01" @default.
- W2013567048 modified "2023-10-16" @default.
- W2013567048 title "Differentiating allotropic LiCoO2/Li2Co2O4: A structural and electrochemical study" @default.
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- W2013567048 doi "https://doi.org/10.1016/j.jpowsour.2014.07.178" @default.
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