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- W2013569069 abstract "1,2-Dimethyl-4,4-dicyanotriafulvene reacts with Fe3(CO)12 in toluène to give the title compound, which is formed by insertion of a Fe(CO)4 group into the three-membered ring system. Simultaneously one cyano group is converted to an amino group. An additional Fe(CO)3 group is coordinated to the ferracyclopentadiene moiety. The complex crystallized from acetonitrile contains one mole of the solvent. Its crystal structure (space group P11) has been determined by X-ray diffraction (R = 0.036). 1,2-Dimethyl-4,4-dicyan-triafulven reagiert mit Fe3(CO)12 in Toluol zur Titelverbindung. Sie bildet sich durch Einsehiebung einer Fe(CO)4-Gruppe in das dreigliedrige Ringsystem. Gleichzeitig entsteht aus einer Cyan-Gruppe eine Amino-Gruppe. Eine zusätzliche Fe(CO)3-Gruppe ist an den Ferracyclopentadien-Teil koordiniert. Der aus Acetonitril kristallisierte Komplex enthält ein Mol des Lösungsmittels. Seine Kristallstruktur (Raumgruppe P1) wurde röntgenographisch bestimmt (R = O.036)." @default.
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- W2013569069 date "1978-05-01" @default.
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- W2013569069 title "Triafulvene als komplexliganden. Reaktion von 1,2-dimethyl-4,4-dicyan-triafulven mit dodecacarbonyltrieisen; strukturaufklärung von tricarbonyl-2,6—8-η4-[1-tricarbonylferra-3-oxa-4-amino-5-cyan-7,8-dimethyl-bicyclo[3.3.02,6]octa-2,4,7-trien] eisen(FeFe)" @default.
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- W2013569069 doi "https://doi.org/10.1016/s0022-328x(00)91923-5" @default.
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