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- W2013570571 abstract "The electron binding energies and relaxation dynamics of water cluster anions (H(2)O)(n)(-) (11 ≤ n ≤ 80) formed in co-expansions with neon were investigated using one-photon and time-resolved photoelectron imaging. Unlike previous experiments with argon, water cluster anions exhibit only one isomer class, the tightly bound isomer I with approximately the same binding energy as clusters formed in argon. This result, along with a decrease in the internal conversion lifetime of excited (H(2)O)(n)(-) (25 ≤ n ≤ 40), indicates that clusters are vibrationally warmer when formed in neon. Over the ranges studied, the vertical detachment energies and lifetimes appear to converge to previously reported values." @default.
- W2013570571 created "2016-06-24" @default.
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- W2013570571 date "2012-03-02" @default.
- W2013570571 modified "2023-10-14" @default.
- W2013570571 title "Thermal effects on energetics and dynamics in water cluster anions (H2O)<i>n</i>−" @default.
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- W2013570571 doi "https://doi.org/10.1063/1.3689439" @default.
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