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- W2013573750 abstract "A new method to prepare annonaceous acetogenins is described in the synthesis of the 14,21-diepimer (14) of squamocin-K. The synthesis utilized the controlled sequence of ring-closing metathesis (RCM) and cross metathesis (CM) reactions to incorporate the stereocenters and skeleton from (3R,4R)-1,5-hexadiene-3,4-diol and 10-chloro-1-decene. The lactone moiety was attached through nucleophilic substitution and achieved the desymmetrization. Inhibitory activities of 14 against human hormone-refractory prostate cancer cell line (PC-3) were also evaluated." @default.
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- W2013573750 date "2013-04-01" @default.
- W2013573750 modified "2023-09-25" @default.
- W2013573750 title "Total synthesis of 14,21-diepi-squamocin-K" @default.
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- W2013573750 doi "https://doi.org/10.1016/j.tet.2013.02.015" @default.
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