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- W2013574122 abstract "Chorismate mutase is thought to accelerate the chorismate-to-prephenate rearrangement in part by significantly lowering the entropy barrier for the reaction. We have determined the activation parameters for the well-characterized Bacillus subtilis chorismate mutase and find that ΔS† (−9.1 ± 1.2 eu) is nearly as unfavorable as the activation entropy for the uncatalyzed process. Our results suggest that chorismate mutase catalysts show greater mechanistic versatility than commonly believed." @default.
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- W2013574122 date "1996-04-01" @default.
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- W2013574122 title "Is chorismate mutase a prototypic entropy trap? - Activation parameters for the Bacillus subtilis enzyme" @default.
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- W2013574122 doi "https://doi.org/10.1016/0040-4039(96)00338-3" @default.
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