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- W2013578089 abstract "The N,N′-dimesitylene substituted o-phenylenediamine 1 reacts with Sn[N(SiMe3)2]2 under formation of the monomeric N-heterocyclic stannylene 2, while the chiral N,N′-substituted o-phenylenediamine 3 reacts with E[N(SiMe3)2]2 (E = Ge, Sn) under formation of the chiral germylene 4 and the chiral stannylene 5, respectively. X-Ray diffraction studies with both stannylenes demonstrated that the metal centers in these compounds are sufficiently sterically protected to prevent interaction between the tin center and the nitrogen donors of adjacent molecules." @default.
- W2013578089 created "2016-06-24" @default.
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- W2013578089 date "2010-01-01" @default.
- W2013578089 modified "2023-10-07" @default.
- W2013578089 title "Sterically demanding and chiral N,N′-disubstituted N-heterocyclic germylenes and stannylenes" @default.
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- W2013578089 doi "https://doi.org/10.1039/c0dt01233e" @default.
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