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- W2013583323 abstract "Solid solutions of M2V2O7 in α-Zn2V2O7 have been prepared and equilibrated at 600°C (M = Mg, Ca, Mn, Co, Ni, Cu, Zn, and Cd). The crystal structure of α-Zn2V2O7 contains only one type of metal site, which is five-coordinated by a somewhat distorted trigonal bipyramid ZnO5 (Gopal & Calvo, 1973). The solubility range is largest for Cu2+ and Co2+ which can substitute for about 35% of the zinc atoms. The cations can be arranged in the following sequence with respect to their solubility in α-Zn2V2O7, which accords well with these ions' preference for five-coordination: Zn2+>> (Cu2+,Co2+) > Mg2+ >(Ni2+, Mn2+) > Cd2+" @default.
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- W2013583323 date "1985-07-01" @default.
- W2013583323 modified "2023-09-26" @default.
- W2013583323 title "Crystal chemistry of α-(Zn,)2V2O7 solid solutions correlation between preference for five-coordination and extension of solid solubility" @default.
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- W2013583323 doi "https://doi.org/10.1016/0025-5408(85)90064-9" @default.
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