Matches in SemOpenAlex for { <https://semopenalex.org/work/W2013583391> ?p ?o ?g. }
- W2013583391 endingPage "452" @default.
- W2013583391 startingPage "447" @default.
- W2013583391 abstract "Pd particle-deposited microporous silica membranes were synthesized to improve hydrogen permselectivity of the microporous silica membrane and to overcome high cost of palladium and crack formation through hydrogen embrittlement. Pd particles below 400 nm in diameter were readily deposited on the microporous silica membrane via a vacuum-impregnation method by using a Pd(C(3)H(5))(C(5)H(5)) precursor. After deposition of Pd particles on the microporous silica membrane, hydrogen permselectivity over nitrogen considerably increased from 11-28 to 30-115 in a permeation temperature range of 25-350 degrees C due to plugging membrane defects and hydrogen adsorption diffusion through the interface between the Pd and silica layer. The activation energy of the Pd-deposited silica membrane (6.32 kJ mol(-1)) was higher than that of the microporous silica membrane (4.22 kJ mol(-1)). In addition, the Pd-particle deposition led to an increase in the permselectivity of He and CO(2) with little chemical affinity for the Pd particles, which indicates that Pd-particle deposition gives the effect of plugging defects such as pinholes or cracks, which could be formed during the membrane preparation. Therefore it is demonstrated that Pd-particle deposition on the silica membrane is effective for induction of the hydrogen adsorption diffusion and plugging membrane defects." @default.
- W2013583391 created "2016-06-24" @default.
- W2013583391 creator A5029182095 @default.
- W2013583391 creator A5050982260 @default.
- W2013583391 creator A5056538172 @default.
- W2013583391 date "2008-09-01" @default.
- W2013583391 modified "2023-10-18" @default.
- W2013583391 title "Synthesis of Pd particle-deposited microporous silica membranes via a vacuum-impregnation method and their gas permeation behavior" @default.
- W2013583391 cites W1594250737 @default.
- W2013583391 cites W1972455675 @default.
- W2013583391 cites W1973214675 @default.
- W2013583391 cites W1977609557 @default.
- W2013583391 cites W1986935071 @default.
- W2013583391 cites W1992054672 @default.
- W2013583391 cites W1995501227 @default.
- W2013583391 cites W1999214882 @default.
- W2013583391 cites W2002857743 @default.
- W2013583391 cites W2013924195 @default.
- W2013583391 cites W2016344709 @default.
- W2013583391 cites W2016517772 @default.
- W2013583391 cites W2027031550 @default.
- W2013583391 cites W2029001724 @default.
- W2013583391 cites W2034485241 @default.
- W2013583391 cites W2039677115 @default.
- W2013583391 cites W2040037870 @default.
- W2013583391 cites W2049382386 @default.
- W2013583391 cites W2053929276 @default.
- W2013583391 cites W2063644450 @default.
- W2013583391 cites W2076511240 @default.
- W2013583391 cites W2078027538 @default.
- W2013583391 cites W2079224645 @default.
- W2013583391 cites W2080261794 @default.
- W2013583391 cites W2080558460 @default.
- W2013583391 cites W2084486183 @default.
- W2013583391 cites W2091067806 @default.
- W2013583391 cites W2092520953 @default.
- W2013583391 doi "https://doi.org/10.1016/j.jcis.2008.06.021" @default.
- W2013583391 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18620361" @default.
- W2013583391 hasPublicationYear "2008" @default.
- W2013583391 type Work @default.
- W2013583391 sameAs 2013583391 @default.
- W2013583391 citedByCount "19" @default.
- W2013583391 countsByYear W20135833912012 @default.
- W2013583391 countsByYear W20135833912013 @default.
- W2013583391 countsByYear W20135833912015 @default.
- W2013583391 countsByYear W20135833912017 @default.
- W2013583391 countsByYear W20135833912019 @default.
- W2013583391 countsByYear W20135833912020 @default.
- W2013583391 countsByYear W20135833912021 @default.
- W2013583391 countsByYear W20135833912022 @default.
- W2013583391 countsByYear W20135833912023 @default.
- W2013583391 crossrefType "journal-article" @default.
- W2013583391 hasAuthorship W2013583391A5029182095 @default.
- W2013583391 hasAuthorship W2013583391A5050982260 @default.
- W2013583391 hasAuthorship W2013583391A5056538172 @default.
- W2013583391 hasConcept C111368507 @default.
- W2013583391 hasConcept C121332964 @default.
- W2013583391 hasConcept C127313418 @default.
- W2013583391 hasConcept C127413603 @default.
- W2013583391 hasConcept C150394285 @default.
- W2013583391 hasConcept C159985019 @default.
- W2013583391 hasConcept C161790260 @default.
- W2013583391 hasConcept C178790620 @default.
- W2013583391 hasConcept C179104552 @default.
- W2013583391 hasConcept C185592680 @default.
- W2013583391 hasConcept C192562407 @default.
- W2013583391 hasConcept C2778517922 @default.
- W2013583391 hasConcept C41625074 @default.
- W2013583391 hasConcept C42360764 @default.
- W2013583391 hasConcept C502130503 @default.
- W2013583391 hasConcept C50670333 @default.
- W2013583391 hasConcept C512968161 @default.
- W2013583391 hasConcept C55493867 @default.
- W2013583391 hasConcept C69357855 @default.
- W2013583391 hasConcept C86381522 @default.
- W2013583391 hasConcept C97355855 @default.
- W2013583391 hasConceptScore W2013583391C111368507 @default.
- W2013583391 hasConceptScore W2013583391C121332964 @default.
- W2013583391 hasConceptScore W2013583391C127313418 @default.
- W2013583391 hasConceptScore W2013583391C127413603 @default.
- W2013583391 hasConceptScore W2013583391C150394285 @default.
- W2013583391 hasConceptScore W2013583391C159985019 @default.
- W2013583391 hasConceptScore W2013583391C161790260 @default.
- W2013583391 hasConceptScore W2013583391C178790620 @default.
- W2013583391 hasConceptScore W2013583391C179104552 @default.
- W2013583391 hasConceptScore W2013583391C185592680 @default.
- W2013583391 hasConceptScore W2013583391C192562407 @default.
- W2013583391 hasConceptScore W2013583391C2778517922 @default.
- W2013583391 hasConceptScore W2013583391C41625074 @default.
- W2013583391 hasConceptScore W2013583391C42360764 @default.
- W2013583391 hasConceptScore W2013583391C502130503 @default.
- W2013583391 hasConceptScore W2013583391C50670333 @default.
- W2013583391 hasConceptScore W2013583391C512968161 @default.
- W2013583391 hasConceptScore W2013583391C55493867 @default.
- W2013583391 hasConceptScore W2013583391C69357855 @default.
- W2013583391 hasConceptScore W2013583391C86381522 @default.
- W2013583391 hasConceptScore W2013583391C97355855 @default.
- W2013583391 hasIssue "2" @default.