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- W2013600442 abstract "Abstract The C60 complexes with decamethylcobaltocene: (Cp*2Co)2C60(C6H4Cl2, C6H5CN)2 (1) and [K · (18‐crown‐6)]2 · C60 · (DMF)4 (2) have been obtained as single crystals by the diffusion method. The IR‐ and UV‐VIS‐NIR‐spectra justify the formation of the C60 2− dianions in these salts. EPR measurements show that the low temperature signals of 1 in the 4–140 K range and 2 in the 4–60 K range have intensity corresponding only to 0.4% and 3.5% from total C60. Because of this, most of the complexes are EPR silent, and, consequently, C60 2− has a diamagnetic singlet (S = 0) state in these temperature ranges. The appearance of a broad EPR signal in the spectum of 1 above 140 K and 2 above ∼60 K is assigned to a thermal population of a close lying excited triplet (S = 1) state. The singlet–triplet energy gap for C60 2− in solid 1 and 2 was estimated to be 730 ± 10 and 300 ± 10 cm−1." @default.
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- W2013600442 date "2005-01-02" @default.
- W2013600442 modified "2023-09-25" @default.
- W2013600442 title "Singlet‐Triplet Transition in the C60 2− Dianion" @default.
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- W2013600442 doi "https://doi.org/10.1081/fst-120027148" @default.
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