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- W2013600521 abstract "A thiol-olefin-cooxygenation (TOCO) radical chain reaction involving ground state molecular oxygen converts 2′-isopropenyl acetophenones directly into cyclic peroxy hemiketal products with three new bonds. Starting with 4-t-butylbenzenethiol, this TOCO process proceeds reproducibly on gram scale in 86% yield. Hemiketal→ketal and sulfide→sulfone transformations finally provide a series of sulfonyl cyclic peroxy ketals. The in vitro antimalarial activities of some of these structurally simple benzo-fused cyclic peroxides are reported." @default.
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- W2013600521 date "2006-04-01" @default.
- W2013600521 modified "2023-09-26" @default.
- W2013600521 title "Ground state oxygen in synthesis of cyclic peroxides. Part 1: Benzo fused ketals" @default.
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- W2013600521 doi "https://doi.org/10.1016/j.tet.2006.02.008" @default.
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