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- W2013602777 abstract "Activity coefficients for NH4Cl in different 1-propanol/water mixed solvents were determined at 25 °C using experimental electromotive force (emf) data of the following galvanic cell: Ag|AgCl|NH4Cl(m),H2O(100−w%),1−PrOH(w%)|NH4+(ISE), in which ISE stands for the ion-selective electrode and w for the mass fraction percent of 1-propanol. The measurements were performed in various mixed 1-propanol/H2O solvent systems containing 0, 10, 20, 30, 40 and 50 mass fraction percent of 1-propanol, respectively. The experimental emf data were obtained by a solvent polymeric PVC ammonium-selective membrane electrode containing a mixture of nonactin/monactin as ionophore and an Ag/AgCl electrode. The non-ideal behavior of the electrolyte system was described, for each mixed solvent system, on the base of the Pitzer ion-interaction model by determining the related coefficients over the molality range from dilute solution to near salt saturation (i.e. about 5.13 mol/kg in pure water or 2.34 mol/kg in 50% mixed 1-propanol/water solvent)." @default.
- W2013602777 created "2016-06-24" @default.
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- W2013602777 date "2005-11-01" @default.
- W2013602777 modified "2023-09-24" @default.
- W2013602777 title "Determination of activity coefficients for NH4Cl in 1-propanol/water mixed solvents by potentiometric measurements" @default.
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- W2013602777 doi "https://doi.org/10.1016/j.molliq.2005.03.004" @default.
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