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- W2013604198 abstract "A new poly (vinyl chloride) (PVC) membrane electrode that is highly selective to <TEX>$Mn^{+2}$</TEX> ions was prepared using N,N'-bis(2'-pyridinecarboxamide)-1,2-ethane (<TEX>$bpenH_2$</TEX>) as a suitable neutral carrier. This concentration range (<TEX>$1.0{times}10^{-5}$</TEX> to <TEX>$1.0{times}10^{-1};M$</TEX>) with Nernstian slope of <TEX>$29.3{pm}0.5;mV$</TEX> per decade. The detection limit and the response time of electrode were <TEX>$8.0{times}10^{-6};M$</TEX> and (<TEX>${leq}15;s$</TEX>) respectively. The membrane can be used for more than two months without observing any divergence. The electrodes exhibited excellent selectivity for <TEX>$Mn^{+2}$</TEX> ion over other mono-, di- and trivalent cations. Selectivity coefficients were determined by the matched potential method (MPM). The electrode can be used in the pH range from 4.0 - 9.0. The isothermal coefficient of this electrode amounted to 0.00023 V/<TEX>$^{circ}C$</TEX>. The stability constant (log <TEX>$K_s$</TEX>) of the <TEX>$Mn^{+2}$</TEX> - <TEX>$bpenH_2$</TEX> complex was determined at <TEX>$25^{circ}C$</TEX> by potentiometric titration in mixed aqueous solution. The proposed electrode was applied to the determination of <TEX>$Mn^{+2}$</TEX> ions in real samples." @default.
- W2013604198 created "2016-06-24" @default.
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- W2013604198 date "2010-10-20" @default.
- W2013604198 modified "2023-10-01" @default.
- W2013604198 title "Manganese(II) Ion-Selective Membrane Electrode Based on N-(2-picolinamido ethyl)-Picolinamide as Neutral Carrier" @default.
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- W2013604198 doi "https://doi.org/10.5012/bkcs.2010.31.10.2980" @default.
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