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- W2013605000 abstract "A study of d π –p π bonding in paramagnetic compounds having the potassium chloroplatinate structure is described. It is shown that the magnetic superexchange effect is approximately proportional to the number of unpaired electrons in t 2g 5 and t 2g 4 systems but there is an irregularity in the t 2g 3 system of potassium chlororhenate. This singularity of the t 2g 3 case is considered to be a result of the orbital and crystal symmetries. The magnetic properties of the compounds are related to the extent of π-bonding stabilization in octahedral complexes having various configurations t 2g n on their central atoms." @default.
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- W2013605000 date "1961-11-01" @default.
- W2013605000 modified "2023-10-16" @default.
- W2013605000 title "π-BONDING IN INORGANIC COMPOUNDS: IV. ROLE OF UNPAIRED ELECTRONS IN HEXAHALO COMPLEXES" @default.
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- W2013605000 doi "https://doi.org/10.1139/v61-313" @default.
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