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- W2013606962 abstract "A new series of oxyfluoride compounds, Sr2RCu2O5F (R = Y,La,Nd,Sm,Gd,Dy,Er and Yb), was successfully synthesized under high pressure of 6 GPa. Electron microscopic observation and X-ray Rietveld analysis indicated that they are essentially isostructural to La2SrCu2O6 (tetragonal, 14/mmm) with a half of apical oxygen sites of CuO5 pyramids replaced by F atoms. Superconductivity occurred in the Nd analogue after Ca substitution for x ≥ 0.5 in Sr2Nd1−xCaxCu2O5F. single-phase sample of the Nd analogue was obtained at x = 0.8 having the highest Tc of 85 K with a Meissner fraction of 6.8% and a shielding fraction of 7.4% at 5 K. These small fractions suggest a small grain size, weak intergrain coupling and/or weak pinning force." @default.
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- W2013606962 date "1996-09-01" @default.
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- W2013606962 title "Synthesis, crystal structures and superconductivity of new copper oxyfluorides, Sr2RCu2O5F (R = Y,La,Nd,Sm,Gd,Dy,Er and Yb)" @default.
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- W2013606962 doi "https://doi.org/10.1016/0921-4534(96)00430-3" @default.
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