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• W2013630595 abstract "Abstract Three novel MnII-VIVO μ-oxalato complexes have been synthesized and characterized, namely [MnVO(ox)2(L)2] [L denotes, 1,10-phenanthroline (phen), 2,2′-bipyridyl (bpy) and 4,4′-dimethyl-2,2′-bipyridyl (Me2bpy), respectively], where ox stands for the oxalate dianion. Based on IR, elemental analysis, conductivity measurements and EPR, these complexes are proposed to have extended oxalato-bridged structures consisting of vanadyl ions and manganese(II) ions, in which each vanadium(IV) has a distorted square-pyramidal environment and each manganese(II) ion has a distorted octahedral environment. The temperature dependence of magnetic susceptibility for [MnVO(ox)2 (phen)2] · H2O was measured over the range 4.1–300 K and the observed data were successfully simulated by an equation based on the spin Hamiltonian operator ( H = −2J S 1 S 2 ), giving the exchange integral J= −30.9 cm−. This indicates antiferromagnetic spin exchange interaction between MnII and VOII ions." @default.
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• W2013630595 date "1996-06-01" @default.
• W2013630595 modified "2023-09-26" @default.
• W2013630595 title "First oxalate-bridged dinuclear MnII-VIVO complexes: Synthesis and magnetic properties" @default.
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• W2013630595 doi "https://doi.org/10.1016/0277-5387(95)00579-x" @default.
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