Matches in SemOpenAlex for { <https://semopenalex.org/work/W2013631233> ?p ?o ?g. }
- W2013631233 endingPage "101" @default.
- W2013631233 startingPage "94" @default.
- W2013631233 abstract "We have conducted a comprehensive comparative study of Ru(bipy)32+, Ru(bipy)2(phen)2+, Ru(bipy)(phen)22+, and Ru(phen)32+ as chemiluminescence and electrochemiluminescence (ECL) reagents, to address several previous conflicting observations and gain a greater insight into their potential for chemical analysis. Clear trends were observed in many of their spectroscopic and electrochemical properties, but the relative chemiluminescence or ECL intensity with a range of analytes/co-reactants is complicated by the contribution of numerous (sometimes opposing) factors. Significantly, the reversibility of cyclic voltammetric responses for the complexes decreased as the number of phenanthroline ligands was increased, due to the lower stability of their ruthenium(III) form in the aqueous solvent. This trend was also evident over a longer timescale when the ruthenium(III) form was spectrophotometrically monitored after chemical oxidation of the ruthenium(II) complexes. In general, the greater stability of Ru(bipy)33+ resulted in lower blank signals, although this effect was less pronounced with ECL, where the reagent is oxidised in the presence of the co-reactants. Nevertheless, this shows the need to compare signal-to-blank ratios or detection limits, rather than the more common comparisons of overall signal intensity for different ruthenium complexes. Furthermore, our results support previous observations that, compared to Ru(bipy)32+, Ru(phen)32+ provides greater ECL and chemiluminescence intensities with oxalate, which in some circumstances translates to superior detection limits, but they do not support the subsequent generalised notion that Ru(phen)32+ is a more sensitive reagent than Ru(bipy)32+ for all analytes." @default.
- W2013631233 created "2016-06-24" @default.
- W2013631233 creator A5002078722 @default.
- W2013631233 creator A5002732430 @default.
- W2013631233 creator A5006731293 @default.
- W2013631233 creator A5012946827 @default.
- W2013631233 creator A5014715335 @default.
- W2013631233 creator A5022628011 @default.
- W2013631233 creator A5041069677 @default.
- W2013631233 creator A5041834035 @default.
- W2013631233 creator A5051546587 @default.
- W2013631233 date "2009-03-01" @default.
- W2013631233 modified "2023-10-12" @default.
- W2013631233 title "Comparison of homoleptic and heteroleptic 2,2′-bipyridine and 1,10-phenanthroline ruthenium complexes as chemiluminescence and electrochemiluminescence reagents in aqueous solution" @default.
- W2013631233 cites W1963945555 @default.
- W2013631233 cites W1966143724 @default.
- W2013631233 cites W1970393749 @default.
- W2013631233 cites W1974896538 @default.
- W2013631233 cites W1977935357 @default.
- W2013631233 cites W1982804449 @default.
- W2013631233 cites W1983352706 @default.
- W2013631233 cites W1984957486 @default.
- W2013631233 cites W1986686113 @default.
- W2013631233 cites W1988114311 @default.
- W2013631233 cites W1993266710 @default.
- W2013631233 cites W1993572775 @default.
- W2013631233 cites W1994014422 @default.
- W2013631233 cites W1997107645 @default.
- W2013631233 cites W2001731195 @default.
- W2013631233 cites W2002253250 @default.
- W2013631233 cites W2004721461 @default.
- W2013631233 cites W2006461919 @default.
- W2013631233 cites W2011826451 @default.
- W2013631233 cites W2013914375 @default.
- W2013631233 cites W2024608500 @default.
- W2013631233 cites W2025529552 @default.
- W2013631233 cites W2036233233 @default.
- W2013631233 cites W2038822441 @default.
- W2013631233 cites W2040501257 @default.
- W2013631233 cites W2054862649 @default.
- W2013631233 cites W2059453556 @default.
- W2013631233 cites W2067717938 @default.
- W2013631233 cites W2069563326 @default.
- W2013631233 cites W2074196165 @default.
- W2013631233 cites W2101774470 @default.
- W2013631233 cites W2102502726 @default.
- W2013631233 cites W2102786148 @default.
- W2013631233 cites W2108012504 @default.
- W2013631233 cites W2114377634 @default.
- W2013631233 cites W2120098839 @default.
- W2013631233 cites W2166212599 @default.
- W2013631233 cites W2318304725 @default.
- W2013631233 cites W4232565521 @default.
- W2013631233 cites W4385795638 @default.
- W2013631233 doi "https://doi.org/10.1016/j.aca.2008.12.042" @default.
- W2013631233 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19200484" @default.
- W2013631233 hasPublicationYear "2009" @default.
- W2013631233 type Work @default.
- W2013631233 sameAs 2013631233 @default.
- W2013631233 citedByCount "28" @default.
- W2013631233 countsByYear W20136312332012 @default.
- W2013631233 countsByYear W20136312332013 @default.
- W2013631233 countsByYear W20136312332014 @default.
- W2013631233 countsByYear W20136312332015 @default.
- W2013631233 countsByYear W20136312332016 @default.
- W2013631233 countsByYear W20136312332017 @default.
- W2013631233 countsByYear W20136312332018 @default.
- W2013631233 countsByYear W20136312332020 @default.
- W2013631233 countsByYear W20136312332022 @default.
- W2013631233 crossrefType "journal-article" @default.
- W2013631233 hasAuthorship W2013631233A5002078722 @default.
- W2013631233 hasAuthorship W2013631233A5002732430 @default.
- W2013631233 hasAuthorship W2013631233A5006731293 @default.
- W2013631233 hasAuthorship W2013631233A5012946827 @default.
- W2013631233 hasAuthorship W2013631233A5014715335 @default.
- W2013631233 hasAuthorship W2013631233A5022628011 @default.
- W2013631233 hasAuthorship W2013631233A5041069677 @default.
- W2013631233 hasAuthorship W2013631233A5041834035 @default.
- W2013631233 hasAuthorship W2013631233A5051546587 @default.
- W2013631233 hasConcept C10390740 @default.
- W2013631233 hasConcept C115624301 @default.
- W2013631233 hasConcept C119128265 @default.
- W2013631233 hasConcept C145802702 @default.
- W2013631233 hasConcept C147789679 @default.
- W2013631233 hasConcept C161790260 @default.
- W2013631233 hasConcept C17525397 @default.
- W2013631233 hasConcept C178790620 @default.
- W2013631233 hasConcept C179104552 @default.
- W2013631233 hasConcept C184651966 @default.
- W2013631233 hasConcept C185592680 @default.
- W2013631233 hasConcept C2777660389 @default.
- W2013631233 hasConcept C2779336533 @default.
- W2013631233 hasConcept C2781083472 @default.
- W2013631233 hasConcept C38965407 @default.
- W2013631233 hasConcept C40875361 @default.
- W2013631233 hasConcept C43617362 @default.
- W2013631233 hasConcept C52859227 @default.
- W2013631233 hasConcept C544153396 @default.