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• W2013634514 abstract "The use of large substituted oligoacenes with dicyanoamido groups as bridging ligands should allow one to design new dinuclear transition metal complexes with relatively strong exchange interactions at very long intermetallic distances. Theoretical methods based on density functional theory predict antiferromagnetic exchange coupling constants of around 200 cm-1 for a nonacene CrIII complex with an intermetallic distance of 33 Å, due to a ligand−metal charge-transfer mechanism. In contrast, the isoelectronic VII complex in which such electron-transfer process is not allowed shows a weak ferromagnetic coupling." @default.
• W2013634514 created "2016-06-24" @default.
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• W2013634514 date "2006-12-06" @default.
• W2013634514 modified "2023-09-23" @default.
• W2013634514 title "Strong Antiferromagnetic Coupling at Long Distance through a Ligand to Metal Charge Transfer Mechanism" @default.
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• W2013634514 doi "https://doi.org/10.1021/jp0668753" @default.
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