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- W2013646031 abstract "The reaction between Re2(C6H5NCOCH3)4Cl2 and water in air yields a blue compound [Re4(C6H5NCOCH3)6(Cl)(μ-O)(μ-OH)(MeOH)3][ReO4]2. It crystallizes in a triclinic cell with a = 12.356(3) A, b = 14.820(6) A, c = 20.064(6) A, α = 103.38(3)°, β = 91.61(2)°, γ = 110.37(2)°, V = 3327(2) A3, and Z = 2. The X-ray crystallography revealed an unprecedented tetranuclear structure together with two perrhenate ions. The tetranuclear dication is formed by two quadruply bonded dirhenium units linked through an oxygen ligand and a hydroxy ligand. One unit uses two rhenium atoms and the other unit uses only one rhenium atom to form a Re−Re−O−Re−OH five-membered ring. The formula of this compound was further confirmed by mass spectral analysis." @default.
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- W2013646031 date "1996-01-01" @default.
- W2013646031 modified "2023-10-14" @default.
- W2013646031 title "A Novel Tetranuclear Compound: Crystal Structure and Mass Spectra of [Re4(C6H5NCOCH3)6(Cl)(μ-O)(μ-OH)(MeOH)3][ReO4]2" @default.
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- W2013646031 doi "https://doi.org/10.1021/ic941092u" @default.
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