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• W2013648344 abstract "Hetero Diels-Alder (HDA) cycloaddition of chiral 1-p-tolylsulfinyl-1,3-pentadiene with benzyl nitrosoformate, under mild conditions, yields 2H-1,2-oxazine 3 with complete regioselectivity and pi-facial diastereoselectivity. Sequential osmylation and protection of the resulting glycol gives the oxazine 5 which is directly transformed into enantiomerically pure 1,4,5-trideoxy-1,4-imino-L-ribitol 8 by reduction under Pd/C." @default.
• W2013648344 created "2016-06-24" @default.
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• W2013648344 date "2000-09-15" @default.
• W2013648344 modified "2023-10-14" @default.
• W2013648344 title "First Asymmetric Hetero Diels−Alder Reaction of 1-Sulfinyl Dienes with Nitroso Derivatives. A New Entry to the Synthesis of Optically Pure 1,4-Imino-<scp>l</scp>-ribitol Derivatives" @default.
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• W2013648344 doi "https://doi.org/10.1021/ol0063611" @default.
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