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- W2013669712 abstract "(-)-Prezizanol (-)-1, (-)-prezizaene (-)-2, isolated from Eremophila georgei Diels, and their epimers, 5 and 6, were synthesized employing β-keto ester 7, readily available from (R)-(+)-pulegone, as a starting material. cis-Epimers, 5 and 6 were obtained with over 95 % stereoselectivity via reductive methylation of enone 22. The natural isomers, (-)-1 and (-)-2, were synthesized via hydroxy-directed hydrogenation of the corresponding allylic alcohol 40 with a homogeneous catalyst." @default.
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- W2013669712 date "1990-01-01" @default.
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- W2013669712 title "Stereocontrolled synthesis of (-)-prezizanol,(-)-prezizaene, their epimers and (-)-allokhusiol" @default.
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- W2013669712 doi "https://doi.org/10.1016/s0040-4020(01)81359-4" @default.
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