Matches in SemOpenAlex for { <https://semopenalex.org/work/W2013670720> ?p ?o ?g. }
Showing items 1 to 89 of
89
with 100 items per page.
- W2013670720 endingPage "2665" @default.
- W2013670720 startingPage "2656" @default.
- W2013670720 abstract "On the basis of density measurements, the determination of apparent and partial molar volumes of the solutes in the title solutions have been carried out previously at and around room temperatures both in H2O and D2O solutions as a function of composition. They showed minima at intermediate compositions, and a number of other properties of these solutions also indicated radical structural changes and differences versus composition. On this basis, we have chosen these solutions to analyze also the solvent partial molar volume and its thermal expansibility, which were not involved in the earlier studies, to these structural changes and differences. To obtain reliable thermal expansibility results, the density measurements were extended down to low temperatures. High precision density measurements of the normal water solutions were carried out in wide temperature [(274.15 to 308.15) K] and molality, m [(0.05 to 3 < 6) mol·kg−1], ranges at closely spaced temperature intervals. From the measured densities, both the solute and the solvent partial molar volumes and their thermal expansibilities were calculated. The results are analyzed in terms of the cage model of the hydrophobic effect, and they are correlated to the solvent excess enthalpy and entropy and to their H2O + D2O isotope effects. Although all the title solutions show dominant “interstitial” solution character, their structure is determined by a variety of structural equilibriums, depending mainly on the polar/apolar balance of the “mixed” solute molecules, on their H-bond donor/acceptor ability, and on the solute/solvent ratio." @default.
- W2013670720 created "2016-06-24" @default.
- W2013670720 creator A5029504099 @default.
- W2013670720 date "2009-06-19" @default.
- W2013670720 modified "2023-10-16" @default.
- W2013670720 title "Thermal Expansion and Structure of 1,3-Dimethylurea, Tetramethylurea, and Tetrabutylammonium Bromide Aqueous Solutions Derived from Density Measurements" @default.
- W2013670720 cites W1967535030 @default.
- W2013670720 cites W1968478133 @default.
- W2013670720 cites W1977308087 @default.
- W2013670720 cites W1978633332 @default.
- W2013670720 cites W1980826986 @default.
- W2013670720 cites W1984884746 @default.
- W2013670720 cites W1987756391 @default.
- W2013670720 cites W2000782727 @default.
- W2013670720 cites W2007190805 @default.
- W2013670720 cites W2012140986 @default.
- W2013670720 cites W2030201310 @default.
- W2013670720 cites W2034265668 @default.
- W2013670720 cites W2035294062 @default.
- W2013670720 cites W2045434416 @default.
- W2013670720 cites W2047788834 @default.
- W2013670720 cites W2075319023 @default.
- W2013670720 cites W2079745558 @default.
- W2013670720 cites W2089897275 @default.
- W2013670720 cites W4247812992 @default.
- W2013670720 cites W4252901688 @default.
- W2013670720 doi "https://doi.org/10.1021/je900164a" @default.
- W2013670720 hasPublicationYear "2009" @default.
- W2013670720 type Work @default.
- W2013670720 sameAs 2013670720 @default.
- W2013670720 citedByCount "26" @default.
- W2013670720 countsByYear W20136707202013 @default.
- W2013670720 countsByYear W20136707202014 @default.
- W2013670720 countsByYear W20136707202015 @default.
- W2013670720 countsByYear W20136707202016 @default.
- W2013670720 countsByYear W20136707202017 @default.
- W2013670720 countsByYear W20136707202018 @default.
- W2013670720 countsByYear W20136707202019 @default.
- W2013670720 countsByYear W20136707202020 @default.
- W2013670720 countsByYear W20136707202021 @default.
- W2013670720 crossrefType "journal-article" @default.
- W2013670720 hasAuthorship W2013670720A5029504099 @default.
- W2013670720 hasConcept C121332964 @default.
- W2013670720 hasConcept C147789679 @default.
- W2013670720 hasConcept C16946580 @default.
- W2013670720 hasConcept C178790620 @default.
- W2013670720 hasConcept C184651966 @default.
- W2013670720 hasConcept C185592680 @default.
- W2013670720 hasConcept C2780471494 @default.
- W2013670720 hasConcept C2911131995 @default.
- W2013670720 hasConcept C3288061 @default.
- W2013670720 hasConcept C35249275 @default.
- W2013670720 hasConcept C47463417 @default.
- W2013670720 hasConcept C88371329 @default.
- W2013670720 hasConcept C97355855 @default.
- W2013670720 hasConceptScore W2013670720C121332964 @default.
- W2013670720 hasConceptScore W2013670720C147789679 @default.
- W2013670720 hasConceptScore W2013670720C16946580 @default.
- W2013670720 hasConceptScore W2013670720C178790620 @default.
- W2013670720 hasConceptScore W2013670720C184651966 @default.
- W2013670720 hasConceptScore W2013670720C185592680 @default.
- W2013670720 hasConceptScore W2013670720C2780471494 @default.
- W2013670720 hasConceptScore W2013670720C2911131995 @default.
- W2013670720 hasConceptScore W2013670720C3288061 @default.
- W2013670720 hasConceptScore W2013670720C35249275 @default.
- W2013670720 hasConceptScore W2013670720C47463417 @default.
- W2013670720 hasConceptScore W2013670720C88371329 @default.
- W2013670720 hasConceptScore W2013670720C97355855 @default.
- W2013670720 hasIssue "9" @default.
- W2013670720 hasLocation W20136707201 @default.
- W2013670720 hasOpenAccess W2013670720 @default.
- W2013670720 hasPrimaryLocation W20136707201 @default.
- W2013670720 hasRelatedWork W1448954368 @default.
- W2013670720 hasRelatedWork W1965922636 @default.
- W2013670720 hasRelatedWork W1976548874 @default.
- W2013670720 hasRelatedWork W1991579233 @default.
- W2013670720 hasRelatedWork W2021260850 @default.
- W2013670720 hasRelatedWork W2094546118 @default.
- W2013670720 hasRelatedWork W2095297734 @default.
- W2013670720 hasRelatedWork W2142077240 @default.
- W2013670720 hasRelatedWork W3086242275 @default.
- W2013670720 hasRelatedWork W3106073434 @default.
- W2013670720 hasVolume "54" @default.
- W2013670720 isParatext "false" @default.
- W2013670720 isRetracted "false" @default.
- W2013670720 magId "2013670720" @default.
- W2013670720 workType "article" @default.