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• W2013677204 abstract "Scanning tunnelling microscopy images with chemical contrast allowed the direct determination of the composition and short-range order behaviour of the clean Pt25Rh75(111), (110), and (100) alloy surfaces. All measurements were performed at room temperature and showed a strong platinum enrichment depending on the preparation temperature. In the top layers of both Pt25Rh75(111) and Pt25Rh75(110)-(1×2) we find a preference for unlike nearest neighbours. Pt25Rh75(100) exhibits after a preparation temperature of 900°C a preference for clustering whereas after a preparation temperature of 600°C, comparable with Pt25Rh75(111) and (110), ordering tendencies appear. Additional investigations of the chemical identity of atoms surrounding hollow positions show mostly small deviations from a random distribution. However, the number of hollow sites surrounded by Rh atoms only can be significantly affected by the short-range order. Pt25Rh75(110) exhibits a (1×2) missing-row reconstruction after annealing above 700°C. After the first annealing of the sputtered surface it is accompanied by mesoscopic long-range ‘waves’ with a height of approximately 2 nm and a wavelength up to 200 nm depending on the preparation temperature." @default.
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• W2013677204 date "1999-11-01" @default.
• W2013677204 modified "2023-10-14" @default.
• W2013677204 title "Pt25Rh75(111), (110), and (100) studied by scanning tunnelling microscopy with chemical contrast" @default.
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• W2013677204 doi "https://doi.org/10.1016/s0039-6028(99)00880-8" @default.
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