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- W2013692445 abstract "Abstract The chloroiodomethyl chain ends of poly(vinyl chloride) (PVC) obtained by the single‐electron‐transfer/degenerative‐chain‐transfer mediated living radical polymerization of vinyl chloride initiated with iodoform were quantitatively functionalized by the reaction with 2‐allyloxyethanol (CH 2 CHCH 2 OCH 2 CH 2 OH). This reaction was performed in dimethyl sulfoxide at 70 °C and was catalyzed by sodium dithionite/sodium bicarbonate. The resulting product is the first example of telechelic PVC [α,ω‐di(hydroxy)PVC]. A possible mechanism for this reaction was suggested. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 1255–1260, 2005" @default.
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- W2013692445 date "2005-02-07" @default.
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- W2013692445 title "Functionalization of the active chain ends of poly(vinyl chloride) obtained by single-electron-transfer/degenerative-chain-transfer mediated living radical polymerization: Synthesis of telechelic ?,?-di(hydroxy)poly(vinyl chloride)" @default.
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- W2013692445 doi "https://doi.org/10.1002/pola.20607" @default.
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