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- W2013714725 abstract "It is considered whether a purely ionic model is suitable to explain the electric crystal field gradients determined by quadrupole splitting of “ionic” crystals such as spinel or corundum. The question arose of how much the field gradients calculated from a point model are influenced by induced higher moments. In the cases of spinel and corundum the electronic dipole and quadrupole moments of the oxygon ions may not be neglected. It appears that in these two compounds the negative contribution of the oxygen dipoles to the field gradient is greater than the positive contributions of all other point charges, so that the resultant is negative. The structural parameters as well as the electronic dipole and quadrupole polarisibility of the ions are known too inexactly to solve this problem uniquely." @default.
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- W2013714725 date "1962-04-01" @default.
- W2013714725 modified "2023-10-16" @default.
- W2013714725 title "Die elektrische Quadrupolaufspaltung von Al<sup>27</sup>in Spinell MgAl<sub>2</sub>O<sub>4</sub>und Korund Al<sub>2</sub>O<sub>3</sub>" @default.
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- W2013714725 doi "https://doi.org/10.1524/zkri.1962.117.1.63" @default.
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