FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2013715079> ?p ?o ?g. }

• W2013715079 endingPage "2554" @default.
• W2013715079 startingPage "2548" @default.
• W2013715079 abstract "Abstract CpCo I ‐olefin‐phosphite and CpCo I ‐bisphosphite complexes were systematically prepared and their reactivity in [2+2+2] cycloaddition reactions compared with highly active [CpCo(H 2 CCHSiMe 3 ) 2 ] ( 1 ). Whereas 1 is an excellent precursor for the synthesis of [CpCo(olefin)(phosphite)] complexes ( 2 a – f ), [CpCo(phosphite) 2 ] complexes ( 3 a – e ) were prepared photochemically from [CpCo(cod)]. The complexes were evaluated in the cyclotrimerization reaction of diynes with nitriles yielding pyridines. For [CpCo(olefin)(phosphite)], as well as some of the [CpCo(phosphite) 2 ] complexes, reaction temperatures as low as 50 °C were sufficient to perform the cycloaddition reaction. A direct comparison showed that the order of reactivity for the complex ligands was olefin 2 >olefin/phosphite>phosphites 2 . The complexes with mixed ligands favorably combine reactivity and stability. Calculations on the ligand dissociation from [CpCo(olefin)(phosphite)] proved that the phosphite is dissociating before the olefin. [CpCo(H 2 CCHSiMe 3 ){P(OPh) 3 }] ( 2 a ) was investigated for the co‐cyclization of diynes and nitriles and found to be an efficient catalyst at rather mild temperatures." @default.
• W2013715079 created "2016-06-24" @default.
• W2013715079 creator A5004427130 @default.
• W2013715079 creator A5049688120 @default.
• W2013715079 creator A5058460794 @default.
• W2013715079 creator A5087368338 @default.
• W2013715079 date "2012-12-18" @default.
• W2013715079 modified "2023-10-18" @default.
• W2013715079 title "Fine-Tuning the Reactivity and Stability by Systematic Ligand Variations in CpCo^IComplexes as Catalysts for [2+2+2] Cycloaddition Reactions" @default.
• W2013715079 cites W1966451323 @default.
• W2013715079 cites W1968548905 @default.
• W2013715079 cites W1974401772 @default.
• W2013715079 cites W1981067184 @default.
• W2013715079 cites W1985920601 @default.
• W2013715079 cites W1989053892 @default.
• W2013715079 cites W1990947721 @default.
• W2013715079 cites W1994139670 @default.
• W2013715079 cites W1996247487 @default.
• W2013715079 cites W2002221932 @default.
• W2013715079 cites W2011049041 @default.
• W2013715079 cites W2012933996 @default.
• W2013715079 cites W2015778172 @default.
• W2013715079 cites W2031996510 @default.
• W2013715079 cites W2043291832 @default.
• W2013715079 cites W2048608882 @default.
• W2013715079 cites W2055452603 @default.
• W2013715079 cites W2056078050 @default.
• W2013715079 cites W2061496878 @default.
• W2013715079 cites W2068927137 @default.
• W2013715079 cites W2072761929 @default.
• W2013715079 cites W2074338492 @default.
• W2013715079 cites W2084901482 @default.
• W2013715079 cites W2091361691 @default.
• W2013715079 cites W2092594270 @default.
• W2013715079 cites W2107886062 @default.
• W2013715079 cites W2111441313 @default.
• W2013715079 cites W2115871753 @default.
• W2013715079 cites W2116194306 @default.
• W2013715079 cites W2123177357 @default.
• W2013715079 cites W2126922076 @default.
• W2013715079 cites W2130472540 @default.
• W2013715079 cites W2133354110 @default.
• W2013715079 cites W2138862884 @default.
• W2013715079 cites W2141977828 @default.
• W2013715079 cites W2142566931 @default.
• W2013715079 cites W2164354872 @default.
• W2013715079 cites W2185166047 @default.
• W2013715079 cites W2319383275 @default.
• W2013715079 cites W2330513115 @default.
• W2013715079 cites W2949536269 @default.
• W2013715079 cites W2950108231 @default.
• W2013715079 cites W2950716928 @default.
• W2013715079 cites W2950784267 @default.
• W2013715079 cites W2951909773 @default.
• W2013715079 cites W2952294200 @default.
• W2013715079 cites W2952713274 @default.
• W2013715079 cites W4234701730 @default.
• W2013715079 cites W4234723157 @default.
• W2013715079 doi "https://doi.org/10.1002/chem.201202946" @default.
• W2013715079 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23255505" @default.
• W2013715079 hasPublicationYear "2012" @default.
• W2013715079 type Work @default.
• W2013715079 sameAs 2013715079 @default.
• W2013715079 citedByCount "51" @default.
• W2013715079 countsByYear W20137150792013 @default.
• W2013715079 countsByYear W20137150792014 @default.
• W2013715079 countsByYear W20137150792015 @default.
• W2013715079 countsByYear W20137150792016 @default.
• W2013715079 countsByYear W20137150792017 @default.
• W2013715079 countsByYear W20137150792018 @default.
• W2013715079 countsByYear W20137150792019 @default.
• W2013715079 countsByYear W20137150792020 @default.
• W2013715079 countsByYear W20137150792021 @default.
• W2013715079 countsByYear W20137150792022 @default.
• W2013715079 countsByYear W20137150792023 @default.
• W2013715079 crossrefType "journal-article" @default.
• W2013715079 hasAuthorship W2013715079A5004427130 @default.
• W2013715079 hasAuthorship W2013715079A5049688120 @default.
• W2013715079 hasAuthorship W2013715079A5058460794 @default.
• W2013715079 hasAuthorship W2013715079A5087368338 @default.
• W2013715079 hasConcept C102931765 @default.
• W2013715079 hasConcept C116569031 @default.
• W2013715079 hasConcept C142724271 @default.
• W2013715079 hasConcept C155647269 @default.
• W2013715079 hasConcept C161790260 @default.
• W2013715079 hasConcept C170493617 @default.
• W2013715079 hasConcept C178790620 @default.
• W2013715079 hasConcept C185592680 @default.
• W2013715079 hasConcept C204787440 @default.
• W2013715079 hasConcept C2776910235 @default.
• W2013715079 hasConcept C2777031885 @default.
• W2013715079 hasConcept C2779664164 @default.
• W2013715079 hasConcept C51886252 @default.
• W2013715079 hasConcept C55493867 @default.
• W2013715079 hasConcept C71924100 @default.
• W2013715079 hasConceptScore W2013715079C102931765 @default.
• W2013715079 hasConceptScore W2013715079C116569031 @default.
• W2013715079 hasConceptScore W2013715079C142724271 @default.

• next