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• W2013733705 abstract "We present the potential energy surfaces of molecular chains of poly(vinylidene-fluoride) (PVDF) and its copolymer with trifluoroethylene P(VDF-TrFE) determined by ab initio calculations. Based on the activation energy, we estimate a Curie temperature for pure PVDF of about 183 °C, which is slightly higher than its melt temperature of 170 °C. The Curie temperature decreases due to introduction of TrFE monomers to PVDF, and the origin of the ferroelectric-paraelectric phase transition of P(VDF-TrFE) is a conformational change between trans and gauche in the VDF segment. No conformational change in the position of TrFE monomers is observed during the phase transition of P(VDF-TrFE), and the gauche conformation is introduced in the all-trans molecule by the TrFE monomers." @default.
• W2013733705 created "2016-06-24" @default.
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• W2013733705 date "2014-05-28" @default.
• W2013733705 modified "2023-09-26" @default.
• W2013733705 title "Ferroelectric phase transition effect of doping trifluoroethylene monomer in poly(vinylidene fluoride)" @default.
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• W2013733705 doi "https://doi.org/10.1063/1.4880296" @default.
• W2013733705 hasPublicationYear "2014" @default.
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