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- W2013738991 abstract "119Sn and 195Pt NMR solution data for the complex anions cis-[PdCl2(SnCl3)2]2−, [Pd(SnCl3)5]3−, [PtCl(SnCl3)3]2−, [Pt(SnCl3)4]2−, [PtH(SnCl3)43− and [PtH(SnCl3)2(PEt3)2]− are reported and compared with those for known related complexes. An increasing number of SnCl3−-ligands per metal results in deshielding of the 119Sn, but a shielding of the 195Pt nuclei. The values 1J(195Pt, 119Sn) and 2J(119Sn, 117Sn) are found to be especially useful probes for molecular structure in this chemistry. Reaction of the complexes sym-trans-[PtCl(μ-Cl)L]2, L = PEt3, PTol3, AsEt3, with one and two equivalents of SnCl2 leads to [PtClL(μ-Cl)2Pt(SnCl3)L] and symtrans-[Pt(μ-Cl)(SnCl3)L]2 respectively, and these compounds have been characterized by 119Sn, 195Pt and 31P NMR spectroscopy." @default.
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- W2013738991 title "119Sn and 195Pt NMR spectroscopy of SnCl3− complexes of platinum and palladium. Some chemistry of the complexes (Ph4P)2 [PtCl4] and [Pt(μ-Cl)Cl(PEt3)]2 with SnCl2" @default.
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- W2013738991 doi "https://doi.org/10.1016/s0020-1693(00)83313-7" @default.
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