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- W2013749073 abstract "For organic photovoltaics (OPV) to realize applications effective strategies to maximize the open-circuit voltage must be developed. Herein we show that solution-processed surface-oxidized Au nanocrystals (o-AuNC) dramatically increase the open-circuit voltage (Voc) of OPV cells based on boron-subphthalocyanine chloride (SubPc)/C60 and chloro-aluminum phthalocyanine (ClAlPc)/C60 heterojunctions when incorporated at the interface between the hole-extracting electrode and the phthalocyanine donor layer. In addition, the cell-to-cell variation in Voc is reduced by up to 10-fold combined with a large reduction in the light intensity dependence of Voc, both of which are important advantages for practical application. The largest increase in Voc is achieved for SubPc/C60-based cells which exhibit a 45% increase to 1.09 ± 0.01 V—an exceptionally high value for a single junction small molecule OPV. Remarkably these improvements are achieved using submonolayers of o-AuNC, which can be rationalized in terms of the exceptionally high work function of o-AuNC (∼5.9 eV) and geometric electric field enhancement effects." @default.
- W2013749073 created "2016-06-24" @default.
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- W2013749073 date "2010-10-05" @default.
- W2013749073 modified "2023-09-25" @default.
- W2013749073 title "Enhancing the Open-Circuit Voltage of Molecular Photovoltaics Using Oxidized Au Nanocrystals" @default.
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- W2013749073 doi "https://doi.org/10.1021/nn101276z" @default.
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