FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2013764243> ?p ?o ?g. }

• W2013764243 endingPage "131" @default.
• W2013764243 startingPage "121" @default.
• W2013764243 abstract "Sulfates are commonly considered to oxidize hydrocarbons to form acid natural gas, whereas the direct oxidants in this process remain controversial. To understand the relation between the initiation of TSR and the speciation of aqueous sulfate, a series of gold-tube hydrous pyrolysis experiments and in situ Raman detections were conducted. The results from hydrous pyrolysis using various sulfate solutions revealed that free SO42- in the formation waters was not able to initiate the direct oxidation of hydrocarbons. The variations of the Raman spectra of MgSO4(aq) with temperature indicated that CIP was formed at temperatures lower than 250 °C; however, a sudden precipitation of magnesium–hydroxide–sulfate–hydrate and an abrupt decrease of the CIP content in solution occurred at higher temperatures (T > 300 °C). This demonstrates that the dominant species of sulfate in solution are CIP and HSO4- in geological and experimental conditions, respectively. Meanwhile, two different mineral buffers, including silica gel and brucite, played distinct roles in the occurrence of TSR involving Mg2+–Na+–SO42-, i.e., the redox reaction was accelerated or inhibited with the presence of silica gel or brucite, respectively. This confirms that CIP is insufficient for initiating TSR and HSO4- is the dominant oxidant for the onset of TSR at the experimental temperature. Moreover, TSR shows more intensive at higher concentration of HSO4-. The effect of additional salts on TSR was also investigated. Raman observations demonstrated that the presence of Mg2+ can promote the formation of CIP in the subsurface. The gold-tube pyrolysis results indicate that dissolved salts play a positive role in the initiation of TSR in the experimental conditions. Hence, CIP was formed, and directly oxidized hydrocarbons or oils in carbonate reservoirs and high concentrations of dissolved salts or cations (especially Mg2+) may account for the low onset temperature of TSR in the subsurface." @default.
• W2013764243 created "2016-06-24" @default.
• W2013764243 creator A5015329340 @default.
• W2013764243 creator A5060377893 @default.
• W2013764243 creator A5064870606 @default.
• W2013764243 creator A5087938995 @default.
• W2013764243 date "2014-04-01" @default.
• W2013764243 modified "2023-09-25" @default.
• W2013764243 title "The speciation of aqueous sulfate and its implication on the initiation mechanisms of TSR at different temperatures" @default.
• W2013764243 cites W1516241922 @default.
• W2013764243 cites W1940707429 @default.
• W2013764243 cites W1965844431 @default.
• W2013764243 cites W1976086351 @default.
• W2013764243 cites W1979165183 @default.
• W2013764243 cites W1979730646 @default.
• W2013764243 cites W1981543262 @default.
• W2013764243 cites W1985039021 @default.
• W2013764243 cites W1985826935 @default.
• W2013764243 cites W2000093983 @default.
• W2013764243 cites W2000859118 @default.
• W2013764243 cites W2001748810 @default.
• W2013764243 cites W2004210882 @default.
• W2013764243 cites W2009889031 @default.
• W2013764243 cites W2010368000 @default.
• W2013764243 cites W2012425818 @default.
• W2013764243 cites W2014070369 @default.
• W2013764243 cites W2017604168 @default.
• W2013764243 cites W2028593781 @default.
• W2013764243 cites W2028847338 @default.
• W2013764243 cites W2030785057 @default.
• W2013764243 cites W2033518493 @default.
• W2013764243 cites W2033681646 @default.
• W2013764243 cites W2033869134 @default.
• W2013764243 cites W2038468368 @default.
• W2013764243 cites W2041184157 @default.
• W2013764243 cites W2047334413 @default.
• W2013764243 cites W2051322359 @default.
• W2013764243 cites W2054140562 @default.
• W2013764243 cites W2054420874 @default.
• W2013764243 cites W2057277840 @default.
• W2013764243 cites W2058592444 @default.
• W2013764243 cites W2062113626 @default.
• W2013764243 cites W2062603052 @default.
• W2013764243 cites W2063210694 @default.
• W2013764243 cites W2063472590 @default.
• W2013764243 cites W2066534372 @default.
• W2013764243 cites W2071291248 @default.
• W2013764243 cites W2077721899 @default.
• W2013764243 cites W2079556926 @default.
• W2013764243 cites W2090885262 @default.
• W2013764243 cites W2092200060 @default.
• W2013764243 cites W2114318257 @default.
• W2013764243 cites W2119766553 @default.
• W2013764243 cites W2120360869 @default.
• W2013764243 cites W2133090777 @default.
• W2013764243 cites W2150925076 @default.
• W2013764243 cites W2169022577 @default.
• W2013764243 cites W2318736561 @default.
• W2013764243 cites W2327561991 @default.
• W2013764243 doi "https://doi.org/10.1016/j.apgeochem.2014.02.001" @default.
• W2013764243 hasPublicationYear "2014" @default.
• W2013764243 type Work @default.
• W2013764243 sameAs 2013764243 @default.
• W2013764243 citedByCount "26" @default.
• W2013764243 countsByYear W20137642432014 @default.
• W2013764243 countsByYear W20137642432016 @default.
• W2013764243 countsByYear W20137642432017 @default.
• W2013764243 countsByYear W20137642432018 @default.
• W2013764243 countsByYear W20137642432019 @default.
• W2013764243 countsByYear W20137642432020 @default.
• W2013764243 countsByYear W20137642432021 @default.
• W2013764243 countsByYear W20137642432022 @default.
• W2013764243 countsByYear W20137642432023 @default.
• W2013764243 crossrefType "journal-article" @default.
• W2013764243 hasAuthorship W2013764243A5015329340 @default.
• W2013764243 hasAuthorship W2013764243A5060377893 @default.
• W2013764243 hasAuthorship W2013764243A5064870606 @default.
• W2013764243 hasAuthorship W2013764243A5087938995 @default.
• W2013764243 hasConcept C120665830 @default.
• W2013764243 hasConcept C121332964 @default.
• W2013764243 hasConcept C178790620 @default.
• W2013764243 hasConcept C179104552 @default.
• W2013764243 hasConcept C184651966 @default.
• W2013764243 hasConcept C185592680 @default.
• W2013764243 hasConcept C2776838516 @default.
• W2013764243 hasConcept C2777216531 @default.
• W2013764243 hasConcept C2778343803 @default.
• W2013764243 hasConcept C36759035 @default.
• W2013764243 hasConcept C40003534 @default.
• W2013764243 hasConcept C543218039 @default.
• W2013764243 hasConcept C55904794 @default.
• W2013764243 hasConcept C78458016 @default.
• W2013764243 hasConcept C86803240 @default.
• W2013764243 hasConceptScore W2013764243C120665830 @default.
• W2013764243 hasConceptScore W2013764243C121332964 @default.
• W2013764243 hasConceptScore W2013764243C178790620 @default.
• W2013764243 hasConceptScore W2013764243C179104552 @default.
• W2013764243 hasConceptScore W2013764243C184651966 @default.

• next