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- W2013769997 abstract "This note presents a lattice-based derivation of the Flory free energy that does not invoke assumptions on the chain character of the solute. This derivation highlights two crucial features of the Flory free energy: (i) The mixing entropy Smix is insensitive to the solute structural details. It depends only on the number of lattice sites occupied by the solute. (ii) In marked distinction, the mixing energy does vary with the topology of the solute, the monomer size and the dimensionality. Our discussion suggests re-examination of the applicability of the Flory free energy to non-polymeric solutions." @default.
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- W2013769997 date "2000-12-01" @default.
- W2013769997 modified "2023-10-16" @default.
- W2013769997 title "The Flory mixing free energy: the effects of solute topology and monomer size" @default.
- W2013769997 doi "https://doi.org/10.1002/1521-3919(20001201)9:9<755::aid-mats755>3.0.co;2-p" @default.
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